The Reaction Kinetics of Neutral Free Radicals and Radical Ions Studied by Laser Flash Photolysis
t-Butoxyl radical has been used as a chemical model for hydrogen abstractions in many enzymatic and biological systems. However, the question has arisen as to how well this reactive intermediate mimics these systems. In addressing this concern, absolute rate constants and Arrhenius parameters for...
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Virginia Tech
2011
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| Online Access: | http://hdl.handle.net/10919/11157 http://scholar.lib.vt.edu/theses/available/etd-04282004-231632 |