DESIGN, SYNTHESIS, AND CALIBRATION OF PEROXYL-RADICAL CLOCKS FOR THE DETERMINATION OF kinh's OF ANTIOXIDANTS AND kp's OF HYDROCARBONS
The projects described herein show the effect of double bond geometry on the Ò-fragmentation of biologically relevant methyl octadecadienoate peroxyl radicals and analogous pentadecadiene peroxyl radicals. From these experiments, two new peroxyl radical clocks were developed. The allylbenzene peroxy...
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Others |
| Language: | en |
| Published: |
VANDERBILT
2006
|
| Subjects: | |
| Online Access: | http://etd.library.vanderbilt.edu/available/etd-03242006-133152/ |