Mechanistic investigations of SpnF- and SpnL-catalyzed cyclizations in the biosynthesis of spinosyn A
Spinosyn A is a particularly interesting natural product due to its structural complexity and potent insecticidal activity. The biosynthetic pathway of spinosyn A is interesting as it has two unusual features, the SpnF-catalyzed (4+2) cycloaddition and the SpnL-catalyzed cyclization to produce the p...
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Format: | Others |
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2015
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Online Access: | http://hdl.handle.net/2152/28735 |