Corrole Synthesis and Catalytic Applications Toward Cobalt(III)-Catalyzed Epoxidation, N-H Insertion, and Cyclopropanation
A variety of bromocorroles, useful precusors for Pd-based cross coupling, were sucessfully synthesized in moderate to good yields. Chiral corroles were also synthesized through use of chiral amides in the aforementioned cross coupling reactions. Cobalt complexes bearing π-acceptor (CNtBu) and σ-dono...
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| Format: | Others |
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Scholar Commons
2010
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| Online Access: | http://scholarcommons.usf.edu/etd/3459 http://scholarcommons.usf.edu/cgi/viewcontent.cgi?article=4654&context=etd |