Chemistry with lithium amide : enantiotopic group & face selective reactions
The accomplishment of the γ-alkylation reaction from β-keto esters of tropinone and the enantioselective aziridine formation from nortropinone is first reported. This opened two new paths to develop tropinone enolate chemistry. One is indirect α-alkylation of tropinone, another is the nucleophilic a...
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Format: | Others |
Language: | en |
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University of Saskatchewan
2007
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Online Access: | http://library.usask.ca/theses/available/etd-10312007-165406/ |