Three-Coordinate Aluminum Alkyl Complexes for Applications in the Polymerization of Cyclic Esters

Bulky 1,4-diamines 1,2-[2,4,6-(CH3)3-C6H3NH-CH2]2-C6H4 and 1,2-(2,6-iPr2C6H3NHCH2)2-C6H4 were utilized as pro-ligands for the formation of novel three-coordinate aluminum alkyl compounds with the general formula [(1,4-diamido)AlR], where R = Me or Et. The synthesis of analogous aluminum hydrides wa...

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Bibliographic Details
Other Authors: Foley, Stephen
Language:English
Published: 2015
Subjects:
Online Access:http://hdl.handle.net/10388/ETD-2014-05-1556