Photoinitiated Radical Carbonylation Using [11C]Carbon Monoxide : 11C-Labelling of Aliphatic Carboxylic Acids, Esters, and Amides

Photoinitiated Radical Carbonylation Using [11C]Carbon Monoxide : 11C-Labelling of Aliphatic Carboxylic Acids, Esters, and Amides

One-step photoinitiated free radical carbonylation was employed for the rapid (5–7 min) labelling of aliphatic carboxylic acids, esters, and amides with a short-lived positron emitter 11C (t½ = 20.3 min) at the carbonyl position. The labelled compounds were synthesized from alkyl iodides (0.05–0.1 m...

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Bibliographic Details
Main Author: Itsenko, Oleksiy
Format: Doctoral Thesis
Language:English
Published: Uppsala universitet, Kemiska institutionen 2005
Subjects:
Organic chemistry
11C-labelling
radicals
carbonylation
carbon monoxide
solvent effects
sensitizers
sulfoxides
WAY-100635
PET
Organisk kemi
Online Access:http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6021
http://nbn-resolving.de/urn:isbn:91-554-6375-4

Internet

http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6021
http://nbn-resolving.de/urn:isbn:91-554-6375-4

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