Silaborations of Unsaturated Compounds

Silaborations of Unsaturated Compounds

This thesis deals with the development of transition metal-catalyzed silaborations of 1,3-dienes and 1,6-enynes. The first part of the thesis describes the development of the enantioselective 1,4-silaboration of 1,3-cyclohexadiene. A number of chiral metal-ligand complexes were evaluated. Up to 82%...

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Bibliographic Details
Main Author: Gerdin, Martin
Format: Doctoral Thesis
Language:English
Published: KTH, Organisk kemi 2008
Subjects:
allylboration
bismetallation
boron
carbocyclization
catalysis
1
3-diene
enantioselective
6-enyne
interelement
N-heterocyclic carbene
nickel
palladium
phosphine
phosphoramidite
platinum
reaction mechanism
silaboration
silicon
silylborane
stereoselective
Chemistry
Kemi
Online Access:http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-9440
http://nbn-resolving.de/urn:isbn:978-91-7415-151-0

Internet

http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-9440
http://nbn-resolving.de/urn:isbn:978-91-7415-151-0

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