Toughening semicrystalline poly(lactic acid) by morphology alteration

For the first time, a physical method based on polymer crystallization is employed, to overcome the inherent brittleness of poly (L-lactic acid) (PLLA) by kinetically trapping a low Tg continuous amorphous phase. The decrease in mobility as a result of polymer crystallization is used to arrest the r...

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Bibliographic Details
Main Author: Rathi, Sahas R
Language:ENG
Published: ScholarWorks@UMass Amherst 2013
Subjects:
Online Access:https://scholarworks.umass.edu/dissertations/AAI3603142