Photofragment studies of carbon-oxygen and carbon-hydrogen bond activation by transition metal cations
Gas-phase transition metal cations can activate C-C and C-H bonds in hydrocarbons at room temperature. They can even activate C-O bonds in CO2. They thus serve as a relatively simple model for C-C and C-H activating catalysts. A better understanding of the crucial steps and a complete characterizati...
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Language: | ENG |
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ScholarWorks@UMass Amherst
2007
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Online Access: | https://scholarworks.umass.edu/dissertations/AAI3289270 |