Novel group 4 complexes for the polymerization and copolymerization of olefins
A new synthetic route to C-2 bridged indenyl metallocenes utilizing the anion of 1-indanone has been developed. Two new ansa-zirconocene complexes, isopropylidene(cyclopentadienyl)(2-indenyl)ZfCl2 ( 1a) and isopropylidene (cyclopentadienyl)(2-(1-methyl-indenyl))ZrCl 2 (1b) were synthesized and exami...
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| Language: | ENG |
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ScholarWorks@UMass Amherst
2003
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| Online Access: | https://scholarworks.umass.edu/dissertations/AAI3096282 |