The chiral induction of polycarbodiimides through diastereomer formation
The cooperativity of polycarbodiimides was probed at several length scales. Each experiment relies on formation of a predominance of a single-handed helix due to diastereomer formation. Polymerization of N-(R)-2,6-dimethylheptyl-$N\sp\prime$-hexyl carbodiimide, 1 ( ($\alpha$) $\sb{365}$ = +7.6, c =...
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| Language: | ENG |
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ScholarWorks@UMass Amherst
1998
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| Online Access: | https://scholarworks.umass.edu/dissertations/AAI9841921 |