Novel cyclopentanoid annulation sequences : an approach to the synthesis of c19-oxygenated cyathanes

Two cyclopentanoid annulation sequences were developed. In the first sequence, (Z)-lbromo- 3-iodo-2-butene (9) was employed in the preparation of the series of angular allylic alcohols 28-30. Upon treatment with an oxochromium(VI) amine reagent, the allylic alcohols 29 and 30 underwent oxidative...

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Bibliographic Details
Main Author: Cook, Katherine Louise
Format: Others
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/9849