Synthesis and study of chelating diamide complexes of titanium: new alkyne cyclotrimerization catalysts and new electroluminescent oligomers and polymers

Titanium complexes containing a propylene bridged diamide ligand [RN(CH2)3NR]2- (1.6a,b) (a, R = 2,6-(CH3)2C6H3 (BAMP); b, R = 2,6-iPr2C6H3 (BAIP)) were synthesized. The dichloride derivatives, [RN(CH2)3NR]TiCl2 (1.10a,b), were prepared by reacting the silylated diamines R(Me3Si)N(CH2)3N(SiMe3)R...

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Bibliographic Details
Main Author: Kah, Daniel Alverson Tan Kiang
Format: Others
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/9068