Reactions of a dinuclear rhodium hydride complex with silanes
The reactions of silanes with the complex [(dippe)Rh]₂(μ--H)₂,1, (where dippe = 1,2- bis(diisopropylphosphino)ethane) are presented in this thesis. Addition of a single equivalent of a secondary silane (RR'SiH₂), to [(dippe)Rh]₂(μ-H)₂,1, gives the complexes [(dippe)Rh]₂(μ-H)(μ-n²-H-SiRR'...
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| Format: | Others |
| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/6946 |