Synthetic investigations toward metal nitrosyl complexes
Reaction of Cp*W(NO)(CH₂SiMe₃)Cl with AgBF4 in MeCN leads to isolation of [Cp*W(NO)(CH₂SiMe₃)(NCMe)₂]BF₄, 2.1. The reactivity of this complex is explored, in particular, the reaction of 2.1 with H₂0 which results in stepwise hydrolysis of the nitrosyl ligand. Labelling studies with D₂0 and H₂¹⁸O...
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| Format: | Others |
| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/6167 |