The diverse chemistry of some tungsten nitrosyl complexes
The η⁵-C₅H₄iPr ligand imparts unprecedented effects on the physical and chemical properties of (η⁵-C₅H₄iPr)W(NO)(CH₂CMe₃)(η³-CH₂CHCMe₂) (2.3) and its precursors. Specifically, the reaction of (η⁵-C₅H₄iPr)W(NO)(CO)₂ (2.1) with PCl₅ results in the formation of the PCl₃ adduct of the (η⁵-C₅H₄iPr)W(NO)...
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| Language: | English |
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University of British Columbia
2017
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| Online Access: | http://hdl.handle.net/2429/60905 |