Ni-catalyzed ortho-directed trifluoromethylthiolation of aryl chlorides and bromides
This thesis describes a novel method to generate trifluoromethanesulfenyl arene or heteroarene products via Ni-catalyzed ortho-selective C-X (X = Cl or Br) activation. Successful C-X activation requires directing groups, but it is highly selective and allows aryl chlorides to be used and shows an ap...
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| Language: | English |
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University of British Columbia
2015
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| Online Access: | http://hdl.handle.net/2429/52974 |