Mechanism of the chromic acid oxidation of alcohols.
The relative rates of chromic acid oxidation of eight aryltrifluoromethylcarbinols were determined in 77.2% acetic acid medium. The primary deuterium isotope effects for these alcohols ranged from 7.40 for p-tolyltrifluoromethylcarbinol to 12.93 for 3,5-dinitrophenyltrifluoromethylcarbinol at 25°. T...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/38787 |