Total synthesis of steroidal derivatives : synthesis of hydrochrysene analogues and related compounds.
A sequence leading to the total synthesis of cis-syn-cis-dodecahydrochrysene and cis-octahydrochrysene derivatives is described. The synthesis employs the Robinson-Mannich base reaction and the Michael reaction to construct the tetracyclic skeleton. Condensation of 6-methoxy-2-tetralone with 1-dieth...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/38436 |