Addition mechanism of group V hydrides to hexafluorobutyne-2, and the electronic spectra of the resultant adducts
The addition of dimethylarsine to hexafluoro-butyne-2 has previously been shown to give the predominantly trans 1:1 adduct, Me₂AsC(CF₃)=C(CF₃)H. In this work, a mechanistic study was made of the addition of dimethylarsine, as well as other Group V hydrides, to hexafluorobutyne-2. This was done to he...
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Language: | English |
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University of British Columbia
2011
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Online Access: | http://hdl.handle.net/2429/34740 |