Addition mechanism of group V hydrides to hexafluorobutyne-2, and the electronic spectra of the resultant adducts

The addition of dimethylarsine to hexafluoro-butyne-2 has previously been shown to give the predominantly trans 1:1 adduct, Me₂AsC(CF₃)=C(CF₃)H. In this work, a mechanistic study was made of the addition of dimethylarsine, as well as other Group V hydrides, to hexafluorobutyne-2. This was done to he...

Full description

Bibliographic Details
Main Author: Leeder, W. Ross
Language:English
Published: University of British Columbia 2011
Subjects:
Online Access:http://hdl.handle.net/2429/34740