Stereocontrolled radical cyclization reactions to yield exocyclic alkenes
The intramolecular reactions of a number of (E)- and (Z)-3-tri(n-butyl)stannyl-2-alkenoates with ω-alkyl radicals generated from alkyl iodides, epoxides, and aldehydes were investigated. These reactions were found to generate exocyclic alkenes in a stereoselective, and in some cases stereospecific,...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/30998 |