Activation of dihydrogen by ruthenium complexes containing chelating phosphines
The previously reported synthesis of dinuclear mixed-valence ruthenium complexes of general formula Ru₂Cl₅(P-P)₂, P-P = DPPP, DPPB, 5,5-CHIRAPHOS, or R.R-DIOP, has been extended to include other diphosphines: P-P = DPPN, DPPH, rac-DPPCP, rac-DPCYCP, S,S-BDPP, R- and S-BINAP, or S-PHENOP. The complex...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/30822 |