Synthesis, characterisation and reactivity of phosphide and methylidene complexes of iridium
The iridium(III) methyl diarylphosphide complexes, Ir(CH₃PR₂-[N(SiMe₂CH₂PPh₂)₂] (2a: R = phenyl, 2b: R = meta-tolyl) had been prepared previous to this work. The iridium(III) dimethylphosphide complex, Ir(CH₃)PMe₂-[N(SiMe₂CH₂PPh₂)₂], 2c, is readily prepared in situ by transmetallation of the Ir(CH₃)...
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| Language: | English |
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University of British Columbia
2011
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| Online Access: | http://hdl.handle.net/2429/30661 |