Hydrogen and methanol activation by some tertiary phosphine ruthenium complexes
The previously known complexes, RU₂H₄Cl₂(PR₃)₄, have now been correctly reformulated as the η²-H₂ species (η²-H₂)(PR₃)₂Ru(μ-Cl)₂(μ-H)RuH(PR₃)₂ (R = Ph, p-tol), 1a and 1b, and it is confirmed that in solution they are dimeric and undergo no ligand dissociation. Also, a new analogue of complexes of ty...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/29763 |