New types of organometallic oxo and related complexes containing molybdenum and tungsten
Treatment of solutions of the 16-electron dialkyl compounds Cp'M(NO)R₂ (Cp’ = Cp (η⁵-C₅H₅) or Cp* (η⁵-C₅Me₅); M = Mo or W; R = CH₂SiMe₃, CH₂CMe₃, CH₂CMe₂Ph, or Me) with either dioxygen or aqueous hydrogen peroxide in Et₂O at ambient temperatures and pressures produces novel 16-electron dioxo al...
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Language: | English |
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University of British Columbia
2010
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Online Access: | http://hdl.handle.net/2429/29261 |