Bis(hydrocarbyl) and alkylidene complexes of iridium
The iridium(m) bis(hydrocarbyl) complexes Ir(R)R'[N(SiMe₂CH₂PPh₂)₂] for R = CH₃, C₆H₅, CH₂Ph, and R' = CH₃, C₆H₅, CH₂Ph, CH₂CMe₃, CH₂SiMe₃ were synthesized in high yields from the hydrocarbyl halide precursors Ir(R)X [N(SiMe₂CH₂PPh₂)₂], where X = I or Br, by reaction with the appropriate o...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/27593 |