Solution reactions of HX molecules (X = SH, Cl, Br) with dinuclear palladium(I) complexes containing bis(diphenylphosphino)methane
This thesis describes kinetic and spectroscopic studies on the reaction between Pd₂X₂(dpm)₂, 1 (X = CI, a; Br, b; I, c; dpm = bis(diphenylphosph-ino)methane) and HX molecules (X = SH, CI, Br) in solution. The reaction of 1 with hydrogen sulfide leads to the formation of the corresponding μ-sulfide,...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/27390 |