Synthesis, characterization, and reactivity with dioxygen, of Ru(OEP)(DPS)₂ and Ru(OEP)(DecMS)₂ [OEP= dianion of octaethylporphyrin; DPS= diphenylsulphide; DecMS= decylmethylsulphide]
The complexes Ru(OEP)(DPS)₂ (1) and Ru(OEP)(DecHS)₂ (2) were prepared in vacuo on a 100-mg scale by treatment of the dimeric species [Ru(OEP)]₂ (3) with a CH₂CI₂ solution containing a slight excess of the appropriate thioether [OEP= dianion of octaethylporphyrin; DPS= diphenylsulphide; DecMS= decylm...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/26020 |