Exploring and exploiting Ruthenium-porphyrin complexes : functionalization, atropisomerism, small-molecule recognition, catalysis, and biological implications
This thesis represents a contribution to advances in ruthenium-porphyrin chemistry. The synthesis of Ru(carbonyl) porphyrins via a new metallation strategy using hexakis(N,N-dimethylformamide)ruthenium(III) triflate is examined in detail, covering a broad range of porphyrins. Mechanistic insights, a...
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| Language: | English |
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2010
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| Online Access: | http://hdl.handle.net/2429/18618 |