Asymmetric induction in the photochemistry of α-oxoamides and bicycle aryl ketones

Enantioselective photochemical synthesis of a β-lactam (methyl 4-[3-hydroxy-2,2- dimethyl-l-(l-methylethyl)-4-oxo-3-azetidinyl]benzoate) was investigated via the ionic chiral auxiliary method. Solid state photolysis of the chiral salts formed from optically pure amines and the achiral α-oxoamide...

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Bibliographic Details
Main Author: Wang, Keyan
Format: Others
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/16152