Reversible binding of dihydrogen to dinuclear ruthenium complexes containing chelating diphosphines

The preparation of dinuclear mixed-valence ruthenium complexes of general formula Ru₂Cl₅(P-P)₂, previously reported for a range of chelating ditertiary phosphines including chiral systems, has been extended to include compounds of the diphosphine 1,4-bis(dicyclohexylphosphino)butane (P-P = DCYPB). T...

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Bibliographic Details
Main Author: Chau, Daniel Elliot Kwok-Yue
Format: Others
Language:English
Published: 2008
Online Access:http://hdl.handle.net/2429/1299