Asymmetric induction in the photochemistry of 2-benzoyladamantane-2-carboxylic acid derivatives
The photochemistry of β-keto ester 28 has been studied in solution as well as the crystalline state. In both media this compound undergoes Yang photocyclization, followed by a spontaneous retro-aldol ring opening to afford δ-keto ester 42 as the major photoproduct, with both benzoyl and methoxyca...
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| Format: | Others |
| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/10676 |