Synthesis and Characterization of Biomimetic Iron Thiolate Complexes Containing Bulky Tris(isopropyl)silyl Ligand Related to the Active Site of [FeFe]-hydrogenase
碩士 === 中國文化大學 === 化學系應用化學碩士班 === 106 === A series of Fe thiolate carbonyl complexes bearing bdt ligands with OSiiPr3 substituents, including diiron complexes [{µ-3,6-(OSiiPr3)2-bdt}Fe2(CO)6] (bdt = 1,2-benzenedithiolate，1)，[Q][{µ-3,6-(OSiiPr3)2-bdt}(PPh2)Fe2(CO)5] (Q = K+ (2)， TBA+ = nBu4N+ (3)， PPN...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2018
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| Online Access: | http://ndltd.ncl.edu.tw/handle/28353r |