Dimetallic Cooperativity in Regio and Steroselective C－C coupling to form Dimers of Monosubstituted Acetylenes
碩士 === 國立成功大學 === 化學系 === 102 === The reaction of [Ru2(μ-dppm)2(μ-OAc)(CO)4][PF6] (1) with terminal alkynes RC≡CH in room temperature gives the alkyne complexes [Ru2(μ-dppm)2(μ-η1,η2-C2R)(CO)4][PF6] ( R = Ph (2)；Tol (3) ) . complex 1 reacts with terminal alkynes RC≡CH ( R = Ph；Tol ) in MeOH reflux t...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2014
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| Online Access: | http://ndltd.ncl.edu.tw/handle/76469549081409681498 |