Hypervalent Iodine Mediated Aziridination and Sulfoximination. Concise Synthesis of (+)- and (–)-Shikimic acids, (+)- and (–)-Quinic acids, (+)- and (–)-4-epi-Shikimic acids, (+)- and (–)-Phenylthioconduritol F, (+)- and (+)- and (–)-MK-7607 and Synthetic Studies toward (+)-Pancratistatin, (+)-trans-Dihydronarciclasine and (–)-Oseltamivir.
博士 === 國立中興大學 === 化學系所 === 102 === Herein we utilized, for the first time, sodium 2-iodoxybenzoate as a highly specific oxidant for PhthNH2 to create a highly chemoselective aziridination reagent. This method efficiently effects aziridination of electron-rich, electron-deficient, allylic alcohol an...
Main Authors: | , |
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Other Authors: | |
Format: | Others |
Language: | en_US |
Published: |
2014
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Online Access: | http://ndltd.ncl.edu.tw/handle/10862584767527321752 |