Reactivity Study of Low-valent Vanadium and Ruthenium β-Diketiminates
碩士 === 國立清華大學 === 化學系 === 101 === In order to activate dinitrogen, reduction of the trivalent vanadium β-diketiminate (Nacnac)DippVCl2 ((Nacnac)Dipp = HC(C(Me)N-2,6- iPr2C6H3)2) by KC8 in the presence of a σ-donor, such as pyridine or 4-dimethylaminopyridine (DMAP), under dinitrogen atmosphere led t...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2013
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| Online Access: | http://ndltd.ncl.edu.tw/handle/23537058239182854833 |