Synthesis and Reactivity of Multiply-Bonded Ditungsten Complexes

碩士 === 國立清華大學 === 化學系 === 101 === The cation exchange between [Li(THF)4]{W2Cl4[μ-η2-HC(N-2,6-iPr2 C6H3)2]2} (1a) and KI in the presence of 18-crown-6 ether affords [K(18-c-6)]{W2Cl4[μ-η2-HC(N-2,6-iPr2C6H3)2]2} (2). Subsequent reduction of 2 gives the quadruply-bonded ditungsten(II) complex W2H2[μ-K(...

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Bibliographic Details
Main Author: 林展民
Other Authors: 蔡易州
Format: Others
Language:zh-TW
Published: 2013
Online Access:http://ndltd.ncl.edu.tw/handle/95087476236012851597