Mononuclear Ni(III)- / Ni(II)-Thiolate Complexes Coordinated by the Labile Ammonia / Hydrazine Ligands
碩士 === 國立清華大學 === 化學系 === 99 === Complex [NiIII(NH3)(P(o-C6H3-3-SiMe3-2-S)3)] (1) was synthesized by reaction of [PPN][NiIII(Cl)(P(o-C6H3-3-SiMe3-2-S)3)] and NH3 in 1:10 molar ratio. Besides, addition of 18-crown-6-ether assisted the formation of crystals by hydrogen bonds with terminal NH3 and its...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2011
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| Online Access: | http://ndltd.ncl.edu.tw/handle/77352261342126351753 |