Deprotonation Reaction of Aluminum Complexes Which Contain Dianionic Pyrrolyl Ligands: Reactions, Syntheses, and Cyclic Ester Ring Opening Polymerization.
碩士 === 國立彰化師範大學 === 化學系 === 97 === Using bidentate dianionic pyrrolyl ligand, [C4H3NH(2-CH2NHtBu)] to react with AlH3•NMe3 in diethyl ether generated a dimeric aluminum hydride complex, [{C4H3N(2-CH2NtBu)}AlH]2(1) in 68.6 % yield. Using complex 1 as starting material reacting with phenol, aniline, t...
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Format: | Others |
Language: | zh-TW |
Published: |
2009
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Online Access: | http://ndltd.ncl.edu.tw/handle/07548421418837123877 |