Reversibility of [2+2] Cycloaddition in Ruthenium Vinylidene Complexes Containing a Tethering C=C Double Bond
碩士 === 國立臺灣大學 === 化學研究所 === 95 === A series of ruthenium vinylidene complexes {[Ru]=C=CHC(Ar)2CH2CH=CH2} BF4 containing terminal vinyl group were prepared. In chloroform, the cationic complex 3a ([Ru] = CpRu(dppp), Ar = Ph) gradually transforms into 4a at room temperature via a metathesis process. T...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | en_US |
| Published: |
2007
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| Online Access: | http://ndltd.ncl.edu.tw/handle/29182900505774697451 |