Nitrosylation of Biomimetic [4Fe4S] Clusters and Interconversion among Neutral/Anionic Roussin’s Red Ester and Dinitrosyl Iron Complexes
碩士 === 國立清華大學 === 化學系 === 95 === The formation mechanisms of DNIC produced by nitosylation of the biomimetic ferredoxin [Fe4S4(SR)4]2- and [4Fe-4S] cluster precursor[Fe4(SR)10]2– (R = Et, Ph) was exhibited. After isolating [Fe4S3(NO)7]– (2) from nitosylation of [Fe4S4(SR)4]2-, the dinitrosyl or mono...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2007
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| Online Access: | http://ndltd.ncl.edu.tw/handle/36000483925587423151 |