Dinuclear and Mononuclear Nickel-Thiolate Complexes:Model Compounds of [NiFe] Hydrogenases
碩士 === 國立清華大學 === 化學系 === 95 === The reaction of [NiIII(P(o-C6H3-3-SiMe3-2-S)3)]2 and NaBEt3H in 1:1 molar ratio and excess 18-crown-6-ether in THF led to the formation of complex [Na-18-crown-6 -ether][Ni2(P(o-C6H3-3-SiMe3-2-S)3)2] (1). The [PPN]2[NiCl4] and NaSEt in 1:4 molar ratio were dissolved...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2007
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| Online Access: | http://ndltd.ncl.edu.tw/handle/04061277669372098876 |