Synthesis and Characterization of Tris(2-pyridyl)- phosphine and Phosphine Oxide Ligated Chromium Carbonyl and Nitrosyl Complexes. Catalytic Applications to C-C and C-O Formation Reactions
碩士 === 國立中正大學 === 化學所 === 95 === These complexes [A(2-py)3Cr(CO)(3-n)(NO)n](BF4)n, (A = P(O), P; n = 1~3) were quantitatively synthesized in two steps by treating tripodal pyridyl ligands P(2-py)3 and O=P(2-py)3 with Cr(CO)6. The precursor [A(2-py)3Cr(CO)3] obtained in the first step can be prepared...
Main Authors: | , |
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
2006
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Online Access: | http://ndltd.ncl.edu.tw/handle/14443869197919178483 |