Preparation of multinuclear Ruthenium Vinylidene Complexes and Their Deprotonation Reactions
碩士 === 國立臺灣大學 === 化學研究所 === 94 === Treatment of [Ru]-Cl, [Ru] = CpRu(PEt3)2, with phenylacetylene in the presence of KPF6 in methanol affords [Ru]=C=C(H)Ph+ (2) and then deprotonation of 2 by MeONa yields complex [Ru]-C≡C-Ph (3) isolated as yellow solid in high yield. Reactions of 3 with various org...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Others |
| Language: | en_US |
| Published: |
2006
|
| Online Access: | http://ndltd.ncl.edu.tw/handle/17152775044433618155 |