Biomimetic Model Studies on Ni/Fe-Containing Metalloenzymes: [NiFe] Hydrogenase and Fe-Containing Nitrile Hydratase
博士 === 國立清華大學 === 化學系 === 93 === Mononuclear, distorted square planar [NiII(SePh)(P(o-C6H3RS)2(o-C6H3RSH))]- (R = H (I-1), SiMe3 (II-la or II-lb)) with a S－H proton interacting with both nickel and sulfur atoms (Type I) or an intramolecular [Ni…H－S] interaction (Type II) were prepared by reaction of...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | en_US |
| Published: |
2005
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| Online Access: | http://ndltd.ncl.edu.tw/handle/61796168678264927167 |