Dinitrosyl Iron Complexes (DNICs)：Biomimetic model study on degradation and repair of [2Fe2S] cluster
碩士 === 國立清華大學 === 化學系 === 92 === Reaction of [PPN][Fe(CO)3(NO)] and S8 in a 1:1 molar ratio in THF proceeded to give the dinitrosyl iron complex [PPN][S5Fe(NO)2] (1) and the known [PPN]2[S5Fe(μ-S)2FeS5] (2). Nitrosylatin of complex 2 in THF shows that cluster 2 is converted into the dinitrosyl iron...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2004
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| Online Access: | http://ndltd.ncl.edu.tw/handle/szffu2 |