Nickel(II)-thiolate-thiol complex: relevance to [NiFe] hydrogenase
碩士 === 國立清華大學 === 化學系 === 92 === Reaction of Ni(ClO4)2．6H2O with 1 equiv. of P(o-C6H4SH)3 in THF leads to the formation of a dimeric complex, Ni2{P(o-C6H4S)2(o-C6H4SH)}2 (1). Complex 1 contains distorted square planar, diamagnetic Ni(II) centers ligated by a phosphorus, a terminal thiolate, two thio...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2004
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| Online Access: | http://ndltd.ncl.edu.tw/handle/973m33 |