Mononuclear, Dinuclear Iron(Ⅱ)-Thiolate Complexes with Mixed CO/CN- Ligands：the Potential Model Compounds of [Fe]-only Hydrogenases
碩士 === 國立彰化師範大學 === 化學系 === 90 === The tricarbonyl-cyano iron(Ⅱ)-thiolate complex mer- and fac-[PPN] [(CN)(CO)3Fe(S,S-CS)] (1) were prepared by the reaction of K2CS3 and [PPN][Fe(CO)3(CN)I2] which is obtained from oxidation addition of iodine to [Fe(CO)4(CN)]-. Photolysis of complex 1 in...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2002
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| Online Access: | http://ndltd.ncl.edu.tw/handle/61150365374725039429 |