The reaction and determination of bis-phosphine diruthenium complexes

碩士 === 國立成功大學 === 化學系碩博士班 === 90 === [Ru2(μ- dppm)2(μ-OAc)(CO)4][BF4] (8) reacted with two kinds of alkynes at room temperature to afford diruthenium alkyne complexes [Ru2(μ- dppm)2(μ-η1,η2-C2Ph)(CO)4][BF4] (1) and [Ru2(μ- dppm)2 (μ-η1,η2-C2Tol)(CO)4][BF4] (2). Complex 1 and 2 reacted with TMNO to p...

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Bibliographic Details
Main Authors: Wei-Yu Chen, 陳偉裕
Other Authors: Kom-Bei Shiu
Format: Others
Language:zh-TW
Published: 2002
Online Access:http://ndltd.ncl.edu.tw/handle/9tmw64